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Valium is a prescription sedative that is used as a muscle relaxer, according to MedlinePlus. It also helps reduce anxiety and sleeping problems. The medication is comprised of the benzodiazepine diazepam, and is available in both pill and liquid form. Those who smoke cigarettes may have decreased Valium benefits. Possible side effects include a shuffling walk, changes in sex drive and/or appetite, dizziness, dry mouth, diarrhea, and upset stomach Muscle Relaxers give you a sense of relaxation that makes the pain subside. They are prescribed for degenerative diseases such as arthritis or injuries to the muscle. Muscle relaxer medication is usually prescribed along with physical therapy to help the muscle heal. Some of the popular prescribed muscle relaxers are Carisoprodol, diazepam and cyclobenzaprine.